A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

Yukinari Sunatsuki, Yukana Kishima, Tamami Kobayashi, Tomoka Yamaguchi, Takayoshi Suzuki, Masaaki Kojima, J. Krzystek, Markku R. Sundberg

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A series of mononuclear MnII, MnIII, and Mn IV complexes was prepared using a single tripodal ligand (H 3L). Addition of a cation (NH4 +, K+, Na+) to [MnIIIL] showed a pronounced effect on the redox potentials. Different variants of Jahn-Teller distortion, axial elongation and compression, were observed in the MnIII complexes.

Original languageEnglish
Pages (from-to)9149-9151
Number of pages3
JournalChemical Communications
Volume47
Issue number32
DOIs
Publication statusPublished - Aug 28 2011

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Jahn-Teller effect
Manganese
Cations
Elongation
Positive ions
Ligands
Oxidation
Oxidation-Reduction

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese. / Sunatsuki, Yukinari; Kishima, Yukana; Kobayashi, Tamami; Yamaguchi, Tomoka; Suzuki, Takayoshi; Kojima, Masaaki; Krzystek, J.; Sundberg, Markku R.

In: Chemical Communications, Vol. 47, No. 32, 28.08.2011, p. 9149-9151.

Research output: Contribution to journalArticle

Sunatsuki, Y, Kishima, Y, Kobayashi, T, Yamaguchi, T, Suzuki, T, Kojima, M, Krzystek, J & Sundberg, MR 2011, 'A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese', Chemical Communications, vol. 47, no. 32, pp. 9149-9151. https://doi.org/10.1039/c1cc12418h
Sunatsuki, Yukinari ; Kishima, Yukana ; Kobayashi, Tamami ; Yamaguchi, Tomoka ; Suzuki, Takayoshi ; Kojima, Masaaki ; Krzystek, J. ; Sundberg, Markku R. / A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese. In: Chemical Communications. 2011 ; Vol. 47, No. 32. pp. 9149-9151.
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