A relationship between chemiluminescence and reactivity of Wittig type reactions of phosphonate carbanions

Jiro Motoyoshiya, Shuji Tsuboi, Keisuke Kokin, Yutaka Takaguchi, Sadao Hayashi, Hiromu Aoyama

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The chemiluminescence (CL) quantum yields (ΦCL) of oxygenation of 10-methyl-9,10-dihydroacridine-9-phosphonate carbanions depended on the phosphorus substituents. The acridinephosphonate with electron negative phosphorus substituents such as bis(2,2,2-trifluoroethyl)phosphono group showed higher ΦCL, which was considered comparing the reactivity of the phosphonoacetates in the Horner-Wadsworth-Emmons (HWE) reactions involving the corresponding phosphorus substituents.

Original languageEnglish
Pages (from-to)25-29
Number of pages5
JournalHeterocyclic Communications
Volume4
Issue number1
Publication statusPublished - 1998
Externally publishedYes

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Organophosphonates
Chemiluminescence
Phosphorus
Phosphonoacetic Acid
Oxygenation
Quantum yield
Electrons

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

A relationship between chemiluminescence and reactivity of Wittig type reactions of phosphonate carbanions. / Motoyoshiya, Jiro; Tsuboi, Shuji; Kokin, Keisuke; Takaguchi, Yutaka; Hayashi, Sadao; Aoyama, Hiromu.

In: Heterocyclic Communications, Vol. 4, No. 1, 1998, p. 25-29.

Research output: Contribution to journalArticle

Motoyoshiya, Jiro ; Tsuboi, Shuji ; Kokin, Keisuke ; Takaguchi, Yutaka ; Hayashi, Sadao ; Aoyama, Hiromu. / A relationship between chemiluminescence and reactivity of Wittig type reactions of phosphonate carbanions. In: Heterocyclic Communications. 1998 ; Vol. 4, No. 1. pp. 25-29.
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