A relationship between chemiluminescence and reactivity of Wittig type reactions of phosphonate carbanions

Jiro Motoyoshiya, Shuji Tsuboi, Keisuke Kokin, Yutaka Takaguchi, Sadao Hayashi, Hiromu Aoyama

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The chemiluminescence (CL) quantum yields (ΦCL) of oxygenation of 10-methyl-9,10-dihydroacridine-9-phosphonate carbanions depended on the phosphorus substituents. The acridinephosphonate with electron negative phosphorus substituents such as bis(2,2,2-trifluoroethyl)phosphono group showed higher ΦCL, which was considered comparing the reactivity of the phosphonoacetates in the Horner-Wadsworth-Emmons (HWE) reactions involving the corresponding phosphorus substituents.

Original languageEnglish
Pages (from-to)25-29
Number of pages5
JournalHeterocyclic Communications
Volume4
Issue number1
DOIs
Publication statusPublished - Jan 1 1998
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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