A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents

Kazuhiko Takai, Tetsuya Ichiguchi, Shintaro Hikasa

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

A catalytic cycle of a chromium salt in a stereoselective transformation of aldehydes to (E)-l-iodoalkenes using a geminal dichromium reagent, is assembled with zinc, Me3SiCl, and NaI in dioxane.

Original languageEnglish
Pages (from-to)1268-1270
Number of pages3
JournalSynlett
Issue number8
Publication statusPublished - 1999

Fingerprint

Chromium
Aldehydes
Zinc
Salts
1,4-dioxane

Keywords

  • Chromium(II)
  • Geminal dichromium reagent
  • Iodoform, (E)-1-iodoalkene
  • Zinc

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents. / Takai, Kazuhiko; Ichiguchi, Tetsuya; Hikasa, Shintaro.

In: Synlett, No. 8, 1999, p. 1268-1270.

Research output: Contribution to journalArticle

Takai, Kazuhiko ; Ichiguchi, Tetsuya ; Hikasa, Shintaro. / A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents. In: Synlett. 1999 ; No. 8. pp. 1268-1270.
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