A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents

Kazuhiko Takai; Tetsuya Ichiguchi; Shintaro Hikasa

doi:10.1055/s-1999-2829

A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents

Kazuhiko Takai, Tetsuya Ichiguchi, Shintaro Hikasa

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A catalytic cycle of a chromium salt in a stereoselective transformation of aldehydes to (E)-l-iodoalkenes using a geminal dichromium reagent, is assembled with zinc, Me₃SiCl, and NaI in dioxane.

Original language	English
Pages (from-to)	1268-1270
Number of pages	3
Journal	Synlett
Issue number	8
DOIs	https://doi.org/10.1055/s-1999-2829
Publication status	Published - Jan 1 1999

Keywords

Chromium(II)
Geminal dichromium reagent
Iodoform, (E)-1-iodoalkene
Zinc

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1999-2829

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title = "A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents",

abstract = "A catalytic cycle of a chromium salt in a stereoselective transformation of aldehydes to (E)-l-iodoalkenes using a geminal dichromium reagent, is assembled with zinc, Me3SiCl, and NaI in dioxane.",

keywords = "Chromium(II), Geminal dichromium reagent, Iodoform, (E)-1-iodoalkene, Zinc",

author = "Kazuhiko Takai and Tetsuya Ichiguchi and Shintaro Hikasa",

year = "1999",

month = jan,

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doi = "10.1055/s-1999-2829",

language = "English",

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T1 - A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents

AU - Takai, Kazuhiko

AU - Ichiguchi, Tetsuya

AU - Hikasa, Shintaro

PY - 1999/1/1

Y1 - 1999/1/1

N2 - A catalytic cycle of a chromium salt in a stereoselective transformation of aldehydes to (E)-l-iodoalkenes using a geminal dichromium reagent, is assembled with zinc, Me3SiCl, and NaI in dioxane.

AB - A catalytic cycle of a chromium salt in a stereoselective transformation of aldehydes to (E)-l-iodoalkenes using a geminal dichromium reagent, is assembled with zinc, Me3SiCl, and NaI in dioxane.

KW - Chromium(II)

KW - Geminal dichromium reagent

KW - Iodoform, (E)-1-iodoalkene

KW - Zinc

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DO - 10.1055/s-1999-2829

M3 - Article

AN - SCOPUS:0032769892

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JO - Synlett

JF - Synlett

IS - 8

ER -

A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents

Abstract

Keywords

ASJC Scopus subject areas

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