A practical one-pot transformation of triphenylphosphine oxide to triphenylphosphine by reduction of in situ generated triphenylphosphine dichloride

Tomotake Yano, Masakatsu Hoshino, Manabu Kuroboshi, Hideo Tanaka

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

One-pot transformation of triphenylphosphine oxide to triphenylphosphine was achieved by the reaction of triphenylphosphine oxide with oxalyl chloride, which led to the formation of triphenylphosphine dichloride, and subsequent reduction of triphenylphosphine dichloride with a combination of aluminum-catalytic metal salt.

Original languageEnglish
Article numberU10909ST
Pages (from-to)801-803
Number of pages3
JournalSynlett
Issue number5
DOIs
Publication statusPublished - 2010

Fingerprint

Aluminum
Salts
Metals
triphenylphosphine oxide
triphenylphosphine
oxalyl chloride

Keywords

  • Aluminum
  • Multi redox system
  • Reduction
  • Triphenylphosphine
  • Triphenylphosphine oxide

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

A practical one-pot transformation of triphenylphosphine oxide to triphenylphosphine by reduction of in situ generated triphenylphosphine dichloride. / Yano, Tomotake; Hoshino, Masakatsu; Kuroboshi, Manabu; Tanaka, Hideo.

In: Synlett, No. 5, U10909ST, 2010, p. 801-803.

Research output: Contribution to journalArticle

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