A practical one-pot transformation of triphenylphosphine oxide to triphenylphosphine by reduction of in situ generated triphenylphosphine dichloride

Tomotake Yano; Masakatsu Hoshino; Manabu Kuroboshi; Hideo Tanaka

doi:10.1055/s-0029-1219194

A practical one-pot transformation of triphenylphosphine oxide to triphenylphosphine by reduction of in situ generated triphenylphosphine dichloride

Tomotake Yano, Masakatsu Hoshino, Manabu Kuroboshi, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

One-pot transformation of triphenylphosphine oxide to triphenylphosphine was achieved by the reaction of triphenylphosphine oxide with oxalyl chloride, which led to the formation of triphenylphosphine dichloride, and subsequent reduction of triphenylphosphine dichloride with a combination of aluminum-catalytic metal salt.

Original language	English
Article number	U10909ST
Pages (from-to)	801-803
Number of pages	3
Journal	Synlett
Issue number	5
DOIs	https://doi.org/10.1055/s-0029-1219194
Publication status	Published - Mar 15 2010

Keywords

Aluminum
Multi redox system
Reduction
Triphenylphosphine
Triphenylphosphine oxide

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0029-1219194

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abstract = "One-pot transformation of triphenylphosphine oxide to triphenylphosphine was achieved by the reaction of triphenylphosphine oxide with oxalyl chloride, which led to the formation of triphenylphosphine dichloride, and subsequent reduction of triphenylphosphine dichloride with a combination of aluminum-catalytic metal salt.",

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author = "Tomotake Yano and Masakatsu Hoshino and Manabu Kuroboshi and Hideo Tanaka",

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AU - Yano, Tomotake

AU - Hoshino, Masakatsu

AU - Kuroboshi, Manabu

AU - Tanaka, Hideo

PY - 2010/3/15

Y1 - 2010/3/15

N2 - One-pot transformation of triphenylphosphine oxide to triphenylphosphine was achieved by the reaction of triphenylphosphine oxide with oxalyl chloride, which led to the formation of triphenylphosphine dichloride, and subsequent reduction of triphenylphosphine dichloride with a combination of aluminum-catalytic metal salt.

AB - One-pot transformation of triphenylphosphine oxide to triphenylphosphine was achieved by the reaction of triphenylphosphine oxide with oxalyl chloride, which led to the formation of triphenylphosphine dichloride, and subsequent reduction of triphenylphosphine dichloride with a combination of aluminum-catalytic metal salt.

KW - Aluminum

KW - Multi redox system

KW - Reduction

KW - Triphenylphosphine

KW - Triphenylphosphine oxide

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A practical one-pot transformation of triphenylphosphine oxide to triphenylphosphine by reduction of in situ generated triphenylphosphine dichloride

Abstract

Keywords

ASJC Scopus subject areas

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