@article{5b87f8bb1f234e1fbe977c61e7c978e6,
title = "A photochemical hydrogen evolution system combining cyanobacterial photosystem I and platinum nanoparticle-terminated molecular wires",
abstract = "A H2 generation system based on the cyanobacterial photosystem I (PSI) reconstituted with 1,4-naphthoquinone-stabilized Pt nanoparticles (PtNPs) was constructed. Irradiating the system with red light (680 nm) and using sodium L(+)-ascorbate as the sacrificial electron donor generated H2, which was detected by GC. The light-induced H2 generation was observed at a maximum rate of 0.026 mol H2 h11 (mol PSI)11 using 2,6-dichloroindophenol (DCIP) as the mediator. The H2 evolution was increased to 0.053 mol H2 h11 (mol PSI)11 in the presence of cytochrome c (cyt c) as the mediator.",
keywords = "Hydrogen generation, Photosystem I, Platinum nanoparticle",
author = "Mariko Miyachi and Kyoko Okuzono and Daiki Nishiori and Yoshinori Yamanoi and Tatsuya Tomo and Masako Iwai and Allakhverdiev, {Suleyman I.} and Hiroshi Nishihara",
note = "Funding Information: The present work was financially supported by CREST from JST (No. JPMJCR15F2; H.N.), Nippon Sheet Glass Foundation for Materials Science and Engineering (Y.Y.), Precise Measurement Technology Promotion Foundation (Y.Y.), Russian Science Foundation (No. 14-14-00039; S.I.A.), Grant-in-Aids for Scientific Research (S) (No. 26220801; H.N., M.M.), Scientific Research (C) (No. 15K05604; Y.Y. and No. 17K07453; T.T.), Scientific Research on Innovative Areas “Molecular Architectonics: Orchestration of Single Molecules for Novel Functions” (area 2509, Nos. 26110505, 26110506, 16H00957, and 16H00958; H.N., Y.Y.), and “Soft Crystals: Science and Photofunctions of Easy-Responsive Systems with Flexibility and Higher-Ordering” (area 2903, No. 17H06369; Y.Y.) from the Ministry of Education, Culture, Sports, Science and Technology, Japan. Publisher Copyright: {\textcopyright} 2017 The Chemical Society of Japan.",
year = "2017",
doi = "10.1246/cl.170576",
language = "English",
volume = "46",
pages = "1479--1481",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "10",
}