A one-dimensional coordination polymer, BBDTA·InCl4: Possible spin-Peierls transition with high critical temperature of 108 K

Wataru Fujita; Kunio Awaga; Ryusuke Kondo; Seiichi Kagoshima

doi:10.1021/ja060979+

A one-dimensional coordination polymer, BBDTA·InCl₄: Possible spin-Peierls transition with high critical temperature of 108 K

Wataru Fujita, Kunio Awaga, Ryusuke Kondo, Seiichi Kagoshima

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

We have studied the crystal structure and magnetic properties of the organic radical cation salt, BBDTA·InCl₄. This material formed a one-dimensional coordination polymer. Magnetic measurements indicated the spin-Peierls transition-like behavior at 108 K, which was higher than those typically observed for the other organic spin-Peierls materials. The structural aspects of the lattice distortion from X-ray diffraction measurements at 50 K have been discussed.

Original language	English
Pages (from-to)	6016-6017
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	18
DOIs	https://doi.org/10.1021/ja060979+
Publication status	Published - May 10 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "We have studied the crystal structure and magnetic properties of the organic radical cation salt, BBDTA·InCl4. This material formed a one-dimensional coordination polymer. Magnetic measurements indicated the spin-Peierls transition-like behavior at 108 K, which was higher than those typically observed for the other organic spin-Peierls materials. The structural aspects of the lattice distortion from X-ray diffraction measurements at 50 K have been discussed.",

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AU - Fujita, Wataru

AU - Awaga, Kunio

AU - Kondo, Ryusuke

AU - Kagoshima, Seiichi

PY - 2006/5/10

Y1 - 2006/5/10

N2 - We have studied the crystal structure and magnetic properties of the organic radical cation salt, BBDTA·InCl4. This material formed a one-dimensional coordination polymer. Magnetic measurements indicated the spin-Peierls transition-like behavior at 108 K, which was higher than those typically observed for the other organic spin-Peierls materials. The structural aspects of the lattice distortion from X-ray diffraction measurements at 50 K have been discussed.

AB - We have studied the crystal structure and magnetic properties of the organic radical cation salt, BBDTA·InCl4. This material formed a one-dimensional coordination polymer. Magnetic measurements indicated the spin-Peierls transition-like behavior at 108 K, which was higher than those typically observed for the other organic spin-Peierls materials. The structural aspects of the lattice distortion from X-ray diffraction measurements at 50 K have been discussed.

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A one-dimensional coordination polymer, BBDTA·InCl₄: Possible spin-Peierls transition with high critical temperature of 108 K

Abstract

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