Abstract
When dimethyl(phenyl)silanol is subjected to an electron-deficient olefin in the presence of a stoichiometric amount of Pd(OAc)2, substitution of the C-H bond of the olefin by a phenyl group on the silanol occurs in 52- 86% yields. The reactions of several aryl- and alkenylsilanols with several olefins are also found to proceed in the system of 10 mol% of Pa(OAc)2, Cu(OAc)2 (3 mol), LiOAc (2 mol) to give the corresponding products in up to 69% yield.
| Original language | English |
|---|---|
| Pages (from-to) | 7893-7896 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 39 |
| Issue number | 43 |
| DOIs | |
| Publication status | Published - Oct 22 1998 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Hirabayashi, K., Nishihara, Y., Mori, A., & Hiyama, T. (1998). A novel C-C bond forming reaction of aryl- and alkenylsilanols. A halogen-free mizoroki-heck type reaction. Tetrahedron Letters, 39(43), 7893-7896. https://doi.org/10.1016/S0040-4039(98)01750-X