A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand

Takafumi Yoshida, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand was developed. The complex was the first example of transition metal ions having d electrons in which nitrate was coordinated as a bidentate ligand. The compound was prepared from [Ni(No3)2(tmen)],NIT2py and KPF6 and was recrystallized from CH2Cl2/Et2O, producing dark green crystals. The x ray analysis confirmed that nitrate acts as a bidentate ligand in the complex cations.

Original languageEnglish
Pages (from-to)1274-1276
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume57
Issue number11
DOIs
Publication statusPublished - Nov 2001
Externally publishedYes

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Nickel
Nitrates
nitrates
nickel
Ligands
ligands
x ray analysis
Transition metals
Metal ions
Cations
metal ions
Metals
transition metals
X-Rays
Electrons
Ions
cations
X rays
Crystals
crystals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand. / Yoshida, Takafumi; Suzuki, Takayoshi; Kaizaki, Sumio.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 57, No. 11, 11.2001, p. 1274-1276.

Research output: Contribution to journalArticle

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