A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand

Takafumi Yoshida; Takayoshi Suzuki; Sumio Kaizaki

doi:10.1107/S0108270101013725

A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand

Takafumi Yoshida, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand was developed. The complex was the first example of transition metal ions having d electrons in which nitrate was coordinated as a bidentate ligand. The compound was prepared from [Ni(No₃)₂(tmen)],NIT2py and KPF₆ and was recrystallized from CH₂Cl₂/Et₂O, producing dark green crystals. The x ray analysis confirmed that nitrate acts as a bidentate ligand in the complex cations.

Original language	English
Pages (from-to)	1274-1276
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	11
DOIs	https://doi.org/10.1107/S0108270101013725
Publication status	Published - Nov 1 2001
Externally published	Yes

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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10.1107/S0108270101013725

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abstract = "A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand was developed. The complex was the first example of transition metal ions having d electrons in which nitrate was coordinated as a bidentate ligand. The compound was prepared from [Ni(No3)2(tmen)],NIT2py and KPF6 and was recrystallized from CH2Cl2/Et2O, producing dark green crystals. The x ray analysis confirmed that nitrate acts as a bidentate ligand in the complex cations.",

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AU - Suzuki, Takayoshi

AU - Kaizaki, Sumio

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N2 - A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand was developed. The complex was the first example of transition metal ions having d electrons in which nitrate was coordinated as a bidentate ligand. The compound was prepared from [Ni(No3)2(tmen)],NIT2py and KPF6 and was recrystallized from CH2Cl2/Et2O, producing dark green crystals. The x ray analysis confirmed that nitrate acts as a bidentate ligand in the complex cations.

AB - A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand was developed. The complex was the first example of transition metal ions having d electrons in which nitrate was coordinated as a bidentate ligand. The compound was prepared from [Ni(No3)2(tmen)],NIT2py and KPF6 and was recrystallized from CH2Cl2/Et2O, producing dark green crystals. The x ray analysis confirmed that nitrate acts as a bidentate ligand in the complex cations.

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A nitronyl nitroxide complex of nickel(II) with nitrate as a ligand

Abstract

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