A new transformation of silanols. Palladium-catalyzed cross-coupling with organic halides in the presence of silver(I) oxide

Kazunori Hirabayashi, Jun Kawashima, Yasushi Nishihara, Atsunori Mori, Tamejiro Hiyama

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Abstract

(equation presented) The reactions of aryl-and alkenylsilanols with organic halides are found to proceed in a catalyst system of 5 mol % of Pd(PPh3)4 and Ag2O (1 equiv) to give the corresponding coupling products in up to 84% yield. † Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan.

Original languageEnglish
Pages (from-to)299-301
Number of pages3
JournalOrganic Letters
Volume1
Issue number2
Publication statusPublished - Jul 29 1999
Externally publishedYes

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ASJC Scopus subject areas

  • Molecular Medicine

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