A general and efficient method for the preparation of γ-alkoxyallylstannanes via an acetal cleavage

Isao Kadota; Toshimichi Sakaihara; Yoshinori Yamamoto

doi:10.1016/0040-4039(96)00493-5

A general and efficient method for the preparation of γ-alkoxyallylstannanes via an acetal cleavage

Isao Kadota, Toshimichi Sakaihara, Yoshinori Yamamoto

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

The reaction of various alcohols and γ-methoxyallylstannane 3 in the presence of a catalytic amount of CSA afforded mixed acetals in high yields. The treatment of the acetals with TMSI and HMDS produced γ-alkoxyallylstannanes in high yields via elimination of methanol.

Original language	English
Pages (from-to)	3195-3198
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	18
DOIs	https://doi.org/10.1016/0040-4039(96)00493-5
Publication status	Published - Apr 29 1996
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(96)00493-5

Cite this

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title = "A general and efficient method for the preparation of γ-alkoxyallylstannanes via an acetal cleavage",

abstract = "The reaction of various alcohols and γ-methoxyallylstannane 3 in the presence of a catalytic amount of CSA afforded mixed acetals in high yields. The treatment of the acetals with TMSI and HMDS produced γ-alkoxyallylstannanes in high yields via elimination of methanol.",

author = "Isao Kadota and Toshimichi Sakaihara and Yoshinori Yamamoto",

year = "1996",

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doi = "10.1016/0040-4039(96)00493-5",

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T1 - A general and efficient method for the preparation of γ-alkoxyallylstannanes via an acetal cleavage

AU - Kadota, Isao

AU - Sakaihara, Toshimichi

AU - Yamamoto, Yoshinori

PY - 1996/4/29

Y1 - 1996/4/29

N2 - The reaction of various alcohols and γ-methoxyallylstannane 3 in the presence of a catalytic amount of CSA afforded mixed acetals in high yields. The treatment of the acetals with TMSI and HMDS produced γ-alkoxyallylstannanes in high yields via elimination of methanol.

AB - The reaction of various alcohols and γ-methoxyallylstannane 3 in the presence of a catalytic amount of CSA afforded mixed acetals in high yields. The treatment of the acetals with TMSI and HMDS produced γ-alkoxyallylstannanes in high yields via elimination of methanol.

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U2 - 10.1016/0040-4039(96)00493-5

DO - 10.1016/0040-4039(96)00493-5

M3 - Article

AN - SCOPUS:0029865128

SN - 0040-4039

VL - 37

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 18

ER -

A general and efficient method for the preparation of γ-alkoxyallylstannanes via an acetal cleavage

Abstract

ASJC Scopus subject areas

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