A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

Manabu Kuroboshi; Tamejiro Hiyama

doi:10.1016/S0040-4039(00)74682-X

A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Reaction of methyl dithiocarbamates R¹R²N-C(S)SMe with n-Bu₄N⁺H₂F₃^- and N-bromosuccinimide provides trifluoromethylamines R¹R²N-CF₃ in good yields.

Original language	English
Pages (from-to)	4177-4178
Number of pages	2
Journal	Tetrahedron Letters
Volume	33
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(00)74682-X
Publication status	Published - Jul 14 1992
Externally published	Yes

Keywords

dithiocarbamates
oxidative desulfurization-fluorination
trifluoromethylamine

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates",

abstract = "Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N+H2F3- and N-bromosuccinimide provides trifluoromethylamines R1R2N-CF3 in good yields.",

keywords = "dithiocarbamates, oxidative desulfurization-fluorination, trifluoromethylamine",

author = "Manabu Kuroboshi and Tamejiro Hiyama",

year = "1992",

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doi = "10.1016/S0040-4039(00)74682-X",

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T1 - A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

AU - Kuroboshi, Manabu

AU - Hiyama, Tamejiro

PY - 1992/7/14

Y1 - 1992/7/14

N2 - Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N+H2F3- and N-bromosuccinimide provides trifluoromethylamines R1R2N-CF3 in good yields.

AB - Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N+H2F3- and N-bromosuccinimide provides trifluoromethylamines R1R2N-CF3 in good yields.

KW - dithiocarbamates

KW - oxidative desulfurization-fluorination

KW - trifluoromethylamine

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U2 - 10.1016/S0040-4039(00)74682-X

DO - 10.1016/S0040-4039(00)74682-X

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

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ER -

A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

Abstract

Keywords

ASJC Scopus subject areas

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