A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

Manabu Kuroboshi; Tamejiro Hiyama

doi:10.1016/S0040-4039(00)74682-X

A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Reaction of methyl dithiocarbamates R¹R²N-C(S)SMe with n-Bu₄N⁺H₂F₃^- and N-bromosuccinimide provides trifluoromethylamines R¹R²N-CF₃ in good yields.

Original language	English
Pages (from-to)	4177-4178
Number of pages	2
Journal	Tetrahedron Letters
Volume	33
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(00)74682-X
Publication status	Published - Jul 14 1992
Externally published	Yes

Keywords

dithiocarbamates
oxidative desulfurization-fluorination
trifluoromethylamine

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(00)74682-X

Cite this

@article{d935b2e74fa240ffad686f4fba47d91a,

title = "A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates",

abstract = "Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N+H2F3- and N-bromosuccinimide provides trifluoromethylamines R1R2N-CF3 in good yields.",

keywords = "dithiocarbamates, oxidative desulfurization-fluorination, trifluoromethylamine",

author = "Manabu Kuroboshi and Tamejiro Hiyama",

year = "1992",

month = jul,

day = "14",

doi = "10.1016/S0040-4039(00)74682-X",

language = "English",

volume = "33",

pages = "4177--4178",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "29",

}

TY - JOUR

T1 - A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

AU - Kuroboshi, Manabu

AU - Hiyama, Tamejiro

PY - 1992/7/14

Y1 - 1992/7/14

N2 - Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N+H2F3- and N-bromosuccinimide provides trifluoromethylamines R1R2N-CF3 in good yields.

AB - Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N+H2F3- and N-bromosuccinimide provides trifluoromethylamines R1R2N-CF3 in good yields.

KW - dithiocarbamates

KW - oxidative desulfurization-fluorination

KW - trifluoromethylamine

UR - http://www.scopus.com/inward/record.url?scp=0026752265&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0026752265&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)74682-X

DO - 10.1016/S0040-4039(00)74682-X

M3 - Article

AN - SCOPUS:0026752265

VL - 33

SP - 4177

EP - 4178

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 29

ER -

A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this