A facile synthesis of trifluoromethylamines by oxidative desulfurization-fluorination of dithiocarbamates

Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

Reaction of methyl dithiocarbamates R1R2N-C(S)SMe with n-Bu4N+H2F3- and N-bromosuccinimide provides trifluoromethylamines R1R2N-CF3 in good yields.

Original languageEnglish
Pages (from-to)4177-4178
Number of pages2
JournalTetrahedron Letters
Volume33
Issue number29
DOIs
Publication statusPublished - Jul 14 1992
Externally publishedYes

Keywords

  • dithiocarbamates
  • oxidative desulfurization-fluorination
  • trifluoromethylamine

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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