A Facile Synthesis of α,α-Difluoroalkyl Ethers and Carbonyl Fluoride Acetals by Oxidative Desulfurization-Fluorination

M. Kuroboshi; T. Hiyama

doi:10.1055/s-1994-22815

A Facile Synthesis of α,α-Difluoroalkyl Ethers and Carbonyl Fluoride Acetals by Oxidative Desulfurization-Fluorination

M. Kuroboshi, T. Hiyama

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

α,α-Difluoro ethers and carbonyl fluoride acetals were readily prepared from thiocarboxylic O-acid esters and O, O′-disubstituted thiocarbonate, respectively, in moderate to good yields by the action of tetrabutylammonium dihydrogentrifluoride and N-bromosuccinimide or N-iodosuccinimide.

Original language	English
Pages (from-to)	251-252
Number of pages	2
Journal	Synlett
Volume	1994
Issue number	4
DOIs	https://doi.org/10.1055/s-1994-22815
Publication status	Published - Apr 1 1994
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1994-22815

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abstract = "α,α-Difluoro ethers and carbonyl fluoride acetals were readily prepared from thiocarboxylic O-acid esters and O, O′-disubstituted thiocarbonate, respectively, in moderate to good yields by the action of tetrabutylammonium dihydrogentrifluoride and N-bromosuccinimide or N-iodosuccinimide.",

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AB - α,α-Difluoro ethers and carbonyl fluoride acetals were readily prepared from thiocarboxylic O-acid esters and O, O′-disubstituted thiocarbonate, respectively, in moderate to good yields by the action of tetrabutylammonium dihydrogentrifluoride and N-bromosuccinimide or N-iodosuccinimide.

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A Facile Synthesis of α,α-Difluoroalkyl Ethers and Carbonyl Fluoride Acetals by Oxidative Desulfurization-Fluorination

Abstract

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