A coupling reaction of aryltributyltin with olefins mediated by palladium(II) acetate

Kazunori Hirabayashi, Jun Ichi Ando, Yasushi Nishihara, Atsunori Mori, Tamejiro Hiyama

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

Phenytributyltin is found to react with butyl acrylate in the presence of Pd(OAc)2 (10 mol%), Cu(OAc)2 (3 mol), and LiOAc (2 mol) in DMF to afford butyl 3-phenylpropenoate in 77% yield. Methyl vinyl ketone, acrolein, acrylonitrile, and styrene are also applicable to this reaction as a substrate.

Original languageEnglish
Pages (from-to)99-101
Number of pages3
JournalSynlett
Issue number1
Publication statusPublished - 1999
Externally publishedYes

Fingerprint

Acrylonitrile
Acrolein
Styrene
Alkenes
Substrates
n-butyl acrylate
palladium(II) acetate
3-buten-2-one

Keywords

  • Aryltin
  • Copper(II) acetate
  • Lithium acetate
  • Mizoroki-Heck type
  • Palladium(II) acetate

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Hirabayashi, K., Ando, J. I., Nishihara, Y., Mori, A., & Hiyama, T. (1999). A coupling reaction of aryltributyltin with olefins mediated by palladium(II) acetate. Synlett, (1), 99-101.

A coupling reaction of aryltributyltin with olefins mediated by palladium(II) acetate. / Hirabayashi, Kazunori; Ando, Jun Ichi; Nishihara, Yasushi; Mori, Atsunori; Hiyama, Tamejiro.

In: Synlett, No. 1, 1999, p. 99-101.

Research output: Contribution to journalArticle

Hirabayashi, K, Ando, JI, Nishihara, Y, Mori, A & Hiyama, T 1999, 'A coupling reaction of aryltributyltin with olefins mediated by palladium(II) acetate', Synlett, no. 1, pp. 99-101.
Hirabayashi, Kazunori ; Ando, Jun Ichi ; Nishihara, Yasushi ; Mori, Atsunori ; Hiyama, Tamejiro. / A coupling reaction of aryltributyltin with olefins mediated by palladium(II) acetate. In: Synlett. 1999 ; No. 1. pp. 99-101.
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AU - Hiyama, Tamejiro

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