A coupling reaction of aryltributyltin with olefins mediated by palladium(II) acetate

Kazunori Hirabayashi, Jun Ichi Ando, Yasushi Nishihara, Atsunori Mori, Tamejiro Hiyama

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

Phenytributyltin is found to react with butyl acrylate in the presence of Pd(OAc)2 (10 mol%), Cu(OAc)2 (3 mol), and LiOAc (2 mol) in DMF to afford butyl 3-phenylpropenoate in 77% yield. Methyl vinyl ketone, acrolein, acrylonitrile, and styrene are also applicable to this reaction as a substrate.

Original languageEnglish
Pages (from-to)99-101
Number of pages3
JournalSynlett
Issue number1
DOIs
Publication statusPublished - 1999
Externally publishedYes

Keywords

  • Aryltin
  • Copper(II) acetate
  • Lithium acetate
  • Mizoroki-Heck type
  • Palladium(II) acetate

ASJC Scopus subject areas

  • Organic Chemistry

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