A catalytic and α-selective sialylation using novel 5-azido sialyl fluoride

Teruaki Mukaiyama, Hiroki Mandai, Hideki Jona

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Catalytic and α-selective sialylation of several glycosyl acceptors with 5-azido sialyl fluoride 2 was successfully carried out in n-valeronitrile using a combined catalyst system of stannic chloride (SnCl4) and silver perchlorate (AgClO4) (1:2) in the coexistence of MS 5A and the corresponding sialosides were obtained in excellent yields with high α-selectivities.

Original languageEnglish
Pages (from-to)1182-1183
Number of pages2
JournalChemistry Letters
Issue number12
DOIs
Publication statusPublished - Dec 5 2002

ASJC Scopus subject areas

  • Chemistry(all)

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