A bifunctional catalyst for carbon dioxide fixation: Cooperative double activation of epoxides for the synthesis of cyclic carbonates

Tadashi Ema, Yuki Miyazaki, Shohei Koyama, Yuya Yano, Takashi Sakai

Research output: Contribution to journalArticle

187 Citations (Scopus)

Abstract

We have developed a very active bifunctional porphyrin catalyst showing a high turnover number (TON = 103000) for the synthesis of cyclic carbonates from CO 2 and epoxides under solvent-free conditions.

Original languageEnglish
Pages (from-to)4489-4491
Number of pages3
JournalChemical Communications
Volume48
Issue number37
DOIs
Publication statusPublished - May 11 2012

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Carbonates
Epoxy Compounds
Porphyrins
Carbon Monoxide
Carbon Dioxide
Carbon dioxide
Chemical activation
Catalysts

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

A bifunctional catalyst for carbon dioxide fixation : Cooperative double activation of epoxides for the synthesis of cyclic carbonates. / Ema, Tadashi; Miyazaki, Yuki; Koyama, Shohei; Yano, Yuya; Sakai, Takashi.

In: Chemical Communications, Vol. 48, No. 37, 11.05.2012, p. 4489-4491.

Research output: Contribution to journalArticle

Ema, Tadashi ; Miyazaki, Yuki ; Koyama, Shohei ; Yano, Yuya ; Sakai, Takashi. / A bifunctional catalyst for carbon dioxide fixation : Cooperative double activation of epoxides for the synthesis of cyclic carbonates. In: Chemical Communications. 2012 ; Vol. 48, No. 37. pp. 4489-4491.
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