TY - JOUR
T1 - (5,16-Dimethyl-2,6,13,17-tetraazatricyclo-[14,4,01,18,0 7,12]docosane-κ4N)dinitrato-copper(II) trihydrate
AU - Choi, Jong Ha
AU - Suzuki, Takayoshi
AU - Kaizaki, Sumio
PY - 2006/9/1
Y1 - 2006/9/1
N2 - In the title compound, [Cu(NO3)2(C20H 40N4)]·3H2O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu-O bond of 2.746 (2) Å may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form.
AB - In the title compound, [Cu(NO3)2(C20H 40N4)]·3H2O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu-O bond of 2.746 (2) Å may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form.
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U2 - 10.1107/S1600536806034234
DO - 10.1107/S1600536806034234
M3 - Article
AN - SCOPUS:33748519223
VL - 62
SP - m2383-m2385
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 9
ER -