(5,16-Dimethyl-2,6,13,17-tetraazatricyclo-[14,4,01,18,0 7,12]docosane-κ4N)dinitrato-copper(II) trihydrate

Jong Ha Choi; Takayoshi Suzuki; Sumio Kaizaki

doi:10.1107/S1600536806034234

(5,16-Dimethyl-2,6,13,17-tetraazatricyclo-[14,4,0^1,18,0 ^7,12]docosane-κ⁴N)dinitrato-copper(II) trihydrate

Jong Ha Choi, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

In the title compound, [Cu(NO₃)₂(C₂₀H ₄₀N₄)]·3H₂O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu-O bond of 2.746 (2) Å may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form.

Original language	English
Pages (from-to)	m2383-m2385
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	9
DOIs	https://doi.org/10.1107/S1600536806034234
Publication status	Published - Sep 1 2006
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "(5,16-Dimethyl-2,6,13,17-tetraazatricyclo-[14,4,01,18,0 7,12]docosane-κ4N)dinitrato-copper(II) trihydrate",

abstract = "In the title compound, [Cu(NO3)2(C20H 40N4)]·3H2O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu-O bond of 2.746 (2) {\AA} may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form.",

author = "Choi, {Jong Ha} and Takayoshi Suzuki and Sumio Kaizaki",

year = "2006",

month = sep,

day = "1",

doi = "10.1107/S1600536806034234",

language = "English",

volume = "62",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

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TY - JOUR

T1 - (5,16-Dimethyl-2,6,13,17-tetraazatricyclo-[14,4,01,18,0 7,12]docosane-κ4N)dinitrato-copper(II) trihydrate

AU - Choi, Jong Ha

AU - Suzuki, Takayoshi

AU - Kaizaki, Sumio

PY - 2006/9/1

Y1 - 2006/9/1

N2 - In the title compound, [Cu(NO3)2(C20H 40N4)]·3H2O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu-O bond of 2.746 (2) Å may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form.

AB - In the title compound, [Cu(NO3)2(C20H 40N4)]·3H2O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu-O bond of 2.746 (2) Å may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form.

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JO - Acta Crystallographica Section E: Structure Reports Online

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