(5,16-Dimethyl-2,6,13,17-tetraazatricyclo-[14,4,01,18,0 7,12]docosane-κ4N)dinitrato-copper(II) trihydrate

Jong Ha Choi, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

In the title compound, [Cu(NO3)2(C20H 40N4)]·3H2O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu-O bond of 2.746 (2) Å may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form.

Original languageEnglish
Pages (from-to)m2383-m2385
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number9
DOIs
Publication statusPublished - Sep 1 2006
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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