1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane

Masaichi Saito, Hizuru Hashimoto, Tomoyuki Tajima

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number8
DOIs
Publication statusPublished - Aug 2010
Externally publishedYes

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ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

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