Abstract
The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 66 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Aug 2010 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Materials Science(all)
- Chemistry(all)
Cite this
1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane. / Saito, Masaichi; Hashimoto, Hizuru; Tajima, Tomoyuki.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 8, 08.2010.Research output: Contribution to journal › Article
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TY - JOUR
T1 - 1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane
AU - Saito, Masaichi
AU - Hashimoto, Hizuru
AU - Tajima, Tomoyuki
PY - 2010/8
Y1 - 2010/8
N2 - The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.
AB - The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.
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U2 - 10.1107/S1600536810025729
DO - 10.1107/S1600536810025729
M3 - Article
VL - 66
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 8
ER -