1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane

Masaichi Saito; Hizuru Hashimoto; Tomoyuki Tajima

doi:10.1107/S1600536810025729

1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane

Masaichi Saito, Hizuru Hashimoto, Tomoyuki Tajima

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

The title compound, [Sn₂(C₇₂H₉₈)Te ₂(Te₃)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.

Original language	English
Pages (from-to)	m885-m886
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	8
DOIs	https://doi.org/10.1107/S1600536810025729
Publication status	Published - Aug 1 2010
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536810025729

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title = "1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane",

abstract = "The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.",

author = "Masaichi Saito and Hizuru Hashimoto and Tomoyuki Tajima",

year = "2010",

month = aug,

day = "1",

doi = "10.1107/S1600536810025729",

language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - 1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane

AU - Saito, Masaichi

AU - Hashimoto, Hizuru

AU - Tajima, Tomoyuki

PY - 2010/8/1

Y1 - 2010/8/1

N2 - The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.

AB - The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.

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VL - 66

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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