1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane

Masaichi Saito, Hizuru Hashimoto, Tomoyuki Tajima

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number8
DOIs
Publication statusPublished - Aug 2010
Externally publishedYes

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Heptanes
Heptane
heptanes
Conformations
Molecules
rings
boats
Boats
Dihedral angle
seats
dihedral angle
molecules
disorders
Atoms
atoms

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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title = "1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane",
abstract = "The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.",
author = "Masaichi Saito and Hizuru Hashimoto and Tomoyuki Tajima",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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T1 - 1,5-bis[2,6-bis-(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1, 5-distannabicyclo-[3.1.1]heptane

AU - Saito, Masaichi

AU - Hashimoto, Hizuru

AU - Tajima, Tomoyuki

PY - 2010/8

Y1 - 2010/8

N2 - The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.

AB - The title compound, [Sn2(C72H98)Te 2(Te3)], has a cage-like structure with bulky aryl substituents on the Sn atoms. The molecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-molecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te - Sn - Te planes.

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DO - 10.1107/S1600536810025729

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VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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