113Cd MAS and Static NMR Study of Chlorocadmate Glasses

Shinichi Sakida, Hironobu Nakata, Yoji Kawamoto

Research output: Contribution to journalArticle

Abstract

113Cd magic-angle spinning (MAS) and static NMR spectra were measured of fourteen kinds of chlorocadmate glasses to reveal the chlorine coordination environments around Cd2+ in the glasses in detail. The spectra of the glasses suggest that the glass structures are mainly composed of infinite double-chains of edge-shared CdCl6 octahedra, being independent of the CdCl2 content and the kinds of chlorides except for CdCl2. 113Cd MAS and static NMR spectroscopies enabled us to reveal not only chlorine coordination number of Cd but also linkage manners between CdCl6 octahedra in the glasses.

Original languageEnglish
Pages (from-to)786-787
Number of pages2
JournalChemistry Letters
Volume32
Issue number9
Publication statusPublished - Sep 5 2003

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Magic angle spinning
Nuclear magnetic resonance
Glass
Cadmium Chloride
Chlorine
Nuclear magnetic resonance spectroscopy
Chlorides

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Sakida, S., Nakata, H., & Kawamoto, Y. (2003). 113Cd MAS and Static NMR Study of Chlorocadmate Glasses. Chemistry Letters, 32(9), 786-787.

113Cd MAS and Static NMR Study of Chlorocadmate Glasses. / Sakida, Shinichi; Nakata, Hironobu; Kawamoto, Yoji.

In: Chemistry Letters, Vol. 32, No. 9, 05.09.2003, p. 786-787.

Research output: Contribution to journalArticle

Sakida, S, Nakata, H & Kawamoto, Y 2003, '113Cd MAS and Static NMR Study of Chlorocadmate Glasses', Chemistry Letters, vol. 32, no. 9, pp. 786-787.
Sakida, Shinichi ; Nakata, Hironobu ; Kawamoto, Yoji. / 113Cd MAS and Static NMR Study of Chlorocadmate Glasses. In: Chemistry Letters. 2003 ; Vol. 32, No. 9. pp. 786-787.
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