α-substituted unsymmetrical phthalocyanines with one through three ttf units and their optical and electrochemical properties

Takeshi Kimura, Nobuhiro Takahashi, Tomoyuki Tajima, Yutaka Takaguchi

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

α-Substituted unsymmetrical phthalocyanines fused with one through three TTF units were prepared from mixed 3,6-dioctyloxyphthalonitrile and 3,6-dioctylphthalonitrile bearing a TTF unit. The optical and electrochemical properties of the products were determined by UV-vis spectroscopy and cyclic voltammetry. Mono-TTF-annulated phthalocyanine and iodine produced the electron transfer complex which showed the radical cationic character.

Original languageEnglish
Pages (from-to)679-686
Number of pages8
JournalHeterocycles
Volume86
Issue number1
DOIs
Publication statusPublished - Dec 1 2012

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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