α-substituted unsymmetrical phthalocyanines with one through three ttf units and their optical and electrochemical properties

Takeshi Kimura; Nobuhiro Takahashi; Tomoyuki Tajima; Yutaka Takaguchi

doi:10.3987/COM-12-S(N)18

α-substituted unsymmetrical phthalocyanines with one through three ttf units and their optical and electrochemical properties

Takeshi Kimura, Nobuhiro Takahashi, Tomoyuki Tajima, Yutaka Takaguchi

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

α-Substituted unsymmetrical phthalocyanines fused with one through three TTF units were prepared from mixed 3,6-dioctyloxyphthalonitrile and 3,6-dioctylphthalonitrile bearing a TTF unit. The optical and electrochemical properties of the products were determined by UV-vis spectroscopy and cyclic voltammetry. Mono-TTF-annulated phthalocyanine and iodine produced the electron transfer complex which showed the radical cationic character.

Original language	English
Pages (from-to)	679-686
Number of pages	8
Journal	Heterocycles
Volume	86
Issue number	1
DOIs	https://doi.org/10.3987/COM-12-S(N)18
Publication status	Published - 2012

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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abstract = "α-Substituted unsymmetrical phthalocyanines fused with one through three TTF units were prepared from mixed 3,6-dioctyloxyphthalonitrile and 3,6-dioctylphthalonitrile bearing a TTF unit. The optical and electrochemical properties of the products were determined by UV-vis spectroscopy and cyclic voltammetry. Mono-TTF-annulated phthalocyanine and iodine produced the electron transfer complex which showed the radical cationic character.",

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T1 - α-substituted unsymmetrical phthalocyanines with one through three ttf units and their optical and electrochemical properties

AU - Kimura, Takeshi

AU - Takahashi, Nobuhiro

AU - Tajima, Tomoyuki

AU - Takaguchi, Yutaka

PY - 2012

Y1 - 2012

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AB - α-Substituted unsymmetrical phthalocyanines fused with one through three TTF units were prepared from mixed 3,6-dioctyloxyphthalonitrile and 3,6-dioctylphthalonitrile bearing a TTF unit. The optical and electrochemical properties of the products were determined by UV-vis spectroscopy and cyclic voltammetry. Mono-TTF-annulated phthalocyanine and iodine produced the electron transfer complex which showed the radical cationic character.

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α-substituted unsymmetrical phthalocyanines with one through three ttf units and their optical and electrochemical properties

Abstract

ASJC Scopus subject areas

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