• 1975 Citations
  • 27 h-Index
1986 …2019
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Research Output 1986 2019

  • 1975 Citations
  • 27 h-Index
  • 117 Article
  • 1 Conference contribution
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Article
2019

Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination

Kuroboshi, M., Morita, M., Masumoto, Y., Mikasa, M., Toza, R. & Tanaka, H., Jan 1 2019, In : Heterocycles. 98, 7, p. 931-939 9 p.

Research output: Contribution to journalArticle

Open Access
Amination
Permittivity
Toluene
Ammonia
Ether

Synthesis of arylthiochlorocyclotriphosphazenes

Kuroboshi, M., Mikasa, M. & Tanaka, H., Jan 1 2019, In : Heterocycles. 98, 7, p. 940-953 14 p.

Research output: Contribution to journalArticle

Open Access
Sulfhydryl Compounds
Gems
potassium carbonate
hexachlorocyclotriphosphazene
2017

Synthesis of dendrimer-type viologen and its use in Pd-mediated homocoupling of aryl halides

Kuroboshi, M., Kojima, A. & Tanaka, H., Jan 1 2017, In : Heterocycles. 94, 11, p. 2132-2140 9 p.

Research output: Contribution to journalArticle

Viologens
Dendrimers
2,2'-Dipyridyl
Bromides
mesitylene
2015
5 Citations (Scopus)

Diquat derivatives, a precursor of organic reductant

Kuroboshi, M., Kondo, T. & Tanaka, H., 2015, In : Heterocycles. 90, 1, p. 723-729 7 p.

Research output: Contribution to journalArticle

Diquat
Dimerization
Reducing Agents
Palladium
Bromides
1 Citation (Scopus)

Facile Synthesis of Diethyl Azodicarboxylate and Diethylhydrazodicarboxylate via the Sequential Bromination and Hofmann-Type Rearrangement of Ethyl Allophanate

Kawakubo, H., Suzuki, T., Nishino, K., Hara, F., Takano, T., Takebayashi, Y., Onodera, M., Mitsui, A., Yahagi, H., Takayama, H., Kuroboshi, M. & Tanaka, H., 2015, In : Synthetic Communications. 45, 9, p. 1068-1072 5 p.

Research output: Contribution to journalArticle

ethyl allophanate
22 Citations (Scopus)

Functional monomer impurity affects adhesive performance

Yoshihara, K., Nagaoka, N., Okihara, T., Kuroboshi, M., Hayakawa, S., Maruo, Y., Nishigawa, G., De Munck, J., Yoshida, Y. & Van Meerbeek, B., Dec 1 2015, In : Dental Materials. 31, 12, p. 1493-1501 9 p.

Research output: Contribution to journalArticle

Pulse code modulation
Adhesives
Dentin
Monomers
Impurities
10 Citations (Scopus)

Reduction of phosphine oxides to the corresponding phosphine derivatives in Mg/Me3SiCl/DMI system

Kuroboshi, M., Kita, T., Aono, A., Katagiri, T., Kikuchi, S., Yamane, S., Kawakubo, H. & Tanaka, H., Feb 11 2015, In : Tetrahedron Letters. 56, 7, p. 918-920 3 p.

Research output: Contribution to journalArticle

phosphine
Oxides
Derivatives
Phosphines
2013
6 Citations (Scopus)

Amphiphilic viologen: Electrochemical generation of organic reductant and pd-catalyzed reductive coupling of aryl halides in water

Kuroboshi, M., Yamamoto, T. & Tanaka, H., 2013, In : Synlett. 24, 2, p. 197-200 4 p., ST-2012-U0872-L.

Research output: Contribution to journalArticle

Viologens
Reducing Agents
Bromides
Water
2 Citations (Scopus)

Electroreduction of aryl halides loaded on palladium-immobilized activated carbon

Kuroboshi, M., Idei, H., Hara, N., Kokui, Y. & Tanaka, H., May 2013, In : Electrochemistry. 81, 5, p. 359-361 3 p.

Research output: Contribution to journalArticle

Palladium
Activated carbon
4 Citations (Scopus)

Electro-reductive homo-coupling reaction of aryl bromides in PdCl 2(PPh3)2/pyridinium salt double mediatory systems

Tanaka, H., Kuroboshi, M., Kataoka, R. & Suzuki, R., May 2013, In : Electrochemistry. 81, 5, p. 356-358 3 p.

Research output: Contribution to journalArticle

Bromides
Salts
palladium chloride
13 Citations (Scopus)

Viologen as catalytic organic reductant: Electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system

Kuroboshi, M., Shiba, T. & Tanaka, H., Jul 10 2013, In : Tetrahedron Letters. 54, 28, p. 3666-3668 3 p.

Research output: Contribution to journalArticle

Viologens
Dimerization
Reducing Agents
Bromides
2011
14 Citations (Scopus)

Electroreduction of tetra-coordinate phosphonium derivatives; One-pot transformation of triphenylphosphine oxide into triphenylphosphine

Kuroboshi, M., Yano, T., Kamenoue, S., Kawakubo, H. & Tanaka, H., Aug 12 2011, In : Tetrahedron. 67, 32, p. 5825-5831 7 p.

Research output: Contribution to journalArticle

Derivatives
Electrodes
Anodes
Cathodes
Lewis Acids
17 Citations (Scopus)

Electroreduction of triphenylphosphine oxide to triphenylphosphine in the presence of chlorotrimethylsilane

Kawakubo, H., Kuroboshi, M., Yano, T., Kobayashi, K., Kamenoue, S., Akagi, T. & Tanaka, H., 2011, In : Synthesis. 24, p. 4091-4098 8 p., F78211SS.

Research output: Contribution to journalArticle

phosphine
Oxides
Electrons
Platinum
Anions
14 Citations (Scopus)

TMSCl-promoted electroreduction of triphenylphosphine oxide to triphenylphosphine

Tanaka, H., Yano, T., Kobayashi, K., Kamenoue, S., Kuroboshi, M. & Kawakubo, H., 2011, In : Synlett. 4, p. 582-584 3 p., U10210ST.

Research output: Contribution to journalArticle

Electrolysis
Phosphorus
Anodes
Cathodes
triphenylphosphine oxide
2010
38 Citations (Scopus)

A practical one-pot transformation of triphenylphosphine oxide to triphenylphosphine by reduction of in situ generated triphenylphosphine dichloride

Yano, T., Hoshino, M., Kuroboshi, M. & Tanaka, H., 2010, In : Synlett. 5, p. 801-803 3 p., U10909ST.

Research output: Contribution to journalArticle

Aluminum
Salts
Metals
triphenylphosphine oxide
triphenylphosphine
35 Citations (Scopus)

Electroreduction of triphenylphosphine dichloride and the efficient one-pot reductive conversion of phosphine oxide to triphenylphosphine

Yano, T., Kuroboshi, M. & Tanaka, H., Jan 27 2010, In : Tetrahedron Letters. 51, 4, p. 698-701 4 p.

Research output: Contribution to journalArticle

phosphine
Oxides
Electrodes
Platinum
Aluminum
2009
5 Citations (Scopus)

Chemo- and product-selective electrooxidation of 3-(arylthiomethyl)- Δ3-cephems

Tanaka, H., Tokumaru, Y., Fukui, K. I., Kuroboshi, M., Torii, S., Jutand, A. & Amatore, C., 2009, In : Synthesis. 20, p. 3449-3459 11 p.

Research output: Contribution to journalArticle

Electrooxidation
Electrolysis
Oxidation
dimethyl disulfide
7 Citations (Scopus)

Design of redox-mediatory systems for electro-organic synthesis

Tanaka, H., Kuroboshi, M. & Mitsudo, K., Dec 2009, In : Electrochemistry. 77, 12, p. 1002-1009 8 p.

Research output: Contribution to journalArticle

Water
Halogenation
Ions
Glycosylation
Carbapenems

Development of aqueous media for electroorganic synthesis.

Kuroboshi, M., 2009, In : Kagaku to Kogyo. 83, 5, p. 206-214 9 p.

Research output: Contribution to journalArticle

14 Citations (Scopus)

Electroorganic synthesis in oil-in-water (O/W) nanoemulsion: TEMPO-mediated electrooxidation of amphiphilic alcohols in water

Kuroboshi, M., Yoshida, T., Oshitani, J., Gotoh, K. & Tanaka, H., Aug 22 2009, In : Tetrahedron. 65, 34, p. 7177-7185 9 p.

Research output: Contribution to journalArticle

Electrooxidation
Oils
Alcohols
Water
Carboxylic Acids
15 Citations (Scopus)

Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system: Approach to totally closed system

Kuroboshi, M., Goto, K. & Tanaka, H., Mar 2009, In : Synthesis. 6, p. 903-908 6 p., F20808SS.

Research output: Contribution to journalArticle

Electrooxidation
Silica Gel
Silica gel
Alcohols
Water
8 Citations (Scopus)

Electroreductive generation of recyclable organic reductant from N,N′-dioctyl-4,4′-bipyridinium and Pd-catalyzed reductive coupling of aryl halides

Kuroboshi, M., Kobayashi, R., Nakagawa, T. & Tanaka, H., Jan 2009, In : Synlett. 1, p. 85-88 4 p.

Research output: Contribution to journalArticle

Reducing Agents
Bromides
Derivatives
diphenyl
triflimide
2008
2 Citations (Scopus)

Electrooxidative desulfurization/chlorination. A facile synthesis of 4-chloro-2-azetidinones, a potent intermediate for carbapenems

Kuroboshi, M., Miyada, M., Tateyama, S. & Tanaka, H., Nov 1 2008, In : Heterocycles. 76, 2, p. 1471-1484 14 p.

Research output: Contribution to journalArticle

Carbapenems
Chlorination
Halogenation
Desulfurization
Acylation
8 Citations (Scopus)

Recyclable electron transfer system: Electroreduction of viologen in ionic liquids and Pd-catalyzed reductive coupling of aryl halides

Kuroboshi, M., Kuwano, A. & Tanaka, H., Dec 2008, In : Electrochemistry. 76, 12, p. 862-864 3 p.

Research output: Contribution to journalArticle

Viologens
Ionic Liquids
Ionic liquids
Electrons
Catalysts
2007
1 Citation (Scopus)
Carbapenems
Acetaldehyde
Amines
Ligands
18 Citations (Scopus)

Electroorganic synthesis in oil-in-water nanoemulsion: TEMPO-mediated electrooxidation of amphiphilic alcohols in water

Yoshida, T., Kuroboshi, M., Oshitani, J., Gotoh, K. & Tanaka, H., Oct 16 2007, In : Synlett. 17, p. 2691-2694 4 p.

Research output: Contribution to journalArticle

Electrooxidation
Oils
Alcohols
Water
Carboxylic Acids
2006
19 Citations (Scopus)

Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system

Kubota, J., Ido, T., Kuroboshi, M., Tanaka, H., Uchida, T. & Shimamura, K., May 15 2006, In : Tetrahedron. 62, 20, p. 4769-4773 5 p.

Research output: Contribution to journalArticle

Electrooxidation
Polymers
Alcohols
Water
Carboxylic Acids
5 Citations (Scopus)

Electrooxidative N-halogenation of 2-azetidinone derivatives

Tanaka, H., Arai, S. Y., Ishitobi, Y., Kuroboshi, M. & Torii, S., Aug 2006, In : Electrochemistry. 74, 8, p. 656-658 3 p.

Research output: Contribution to journalArticle

Halogenation
Electrolysis
Derivatives
Nucleophiles
Platinum
2005
16 Citations (Scopus)

Electrooxidation of alcohols in an N-Oxyl-immobilized poly(ethylene-co- acrylic acid)/water disperse system

Tanaka, H., Kubota, J., Miyahara, S. & Kuroboshi, M., Sep 15 2005, In : Bulletin of the Chemical Society of Japan. 78, 9, p. 1677-1684 8 p.

Research output: Contribution to journalArticle

Electrooxidation
Alcohols
Water
Carboxylic Acids
Esterification
28 Citations (Scopus)

Electrooxidative glycosylation through C-S bond cleavage of 1-arylthio-2,3-dideoxyglycosides. Synthesis of 2′,3′- dideoxynucleosides

Mitsudo, K., Kawaguchi, T., Miyahara, S., Matsuda, W., Kuroboshi, M. & Tanaka, H., Oct 13 2005, In : Organic Letters. 7, 21, p. 4649-4652 4 p.

Research output: Contribution to journalArticle

Dideoxynucleosides
Glycosylation
Electrooxidation
halides
cleavage
8 Citations (Scopus)

Reductive coupling of aryl bromides using cat. Pd/TDAE system in ionic liquids

Kuroboshi, M., Takeda, T., Motoki, R. & Tanaka, H., Apr 5 2005, In : Chemistry Letters. 34, 4, p. 530-531 2 p.

Research output: Contribution to journalArticle

Ionic Liquids
Bromides
Catalysts
2004
11 Citations (Scopus)

Aluminium as an electron pool for organic synthesis - Multi-metal redox promoted reactions

Tanaka, H. & Kuroboshi, M., Jul 2004, In : Current Organic Chemistry. 8, 11, p. 1027-1056 30 p.

Research output: Contribution to journalArticle

Redox reactions
Aluminum
Metals
Electrons
Reducing Agents
10 Citations (Scopus)

N-oxyl-mediated electrooxidation in ionic liquid. A prominent approach to totally closed system

Kuroboshi, M., Fujisawa, J. & Tanaka, H., Dec 2004, In : Electrochemistry. 72, 12, p. 846-848 3 p.

Research output: Contribution to journalArticle

Ionic Liquids
Electrooxidation
Ionic liquids
Alcohols
Ketones
24 Citations (Scopus)
Silica Gel
Alcohols
Oxidation
Carboxylic Acids
Ketones

Water/fine particle dispersed aqueous electrolytic synthesis.

Kuroboshi, M., 2004, In : Yuki Denkai Gosei no Shintenkai. 2004, p. 216-228 13 p.

Research output: Contribution to journalArticle

21 Citations (Scopus)

Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized polyethylene particles as disperse phase and aqueous NaHCO3/NaBr as disperse media: A totally closed electrolysis system

Tanaka, H., Kubota, J., Itogawa, S. J., Ido, T., Kuroboshi, M., Shimamura, K. & Uchida, T., 2003, In : Synlett. 7, p. 951-954 4 p.

Research output: Contribution to journalArticle

Electrooxidation
Polyethylene
Electrolysis
Alcohols
Nitric Acid
103 Citations (Scopus)

Palladium-catalyzed tetrakis(dimethylamino)ethylene-promoted reductive coupling of aryl halides

Kuroboshi, M., Waki, Y. & Tanaka, H., May 16 2003, In : Journal of Organic Chemistry. 68, 10, p. 3938-3942 5 p.

Research output: Contribution to journalArticle

Palladium
phosphine
Electrons
Bromides
Catalysts
2002
22 Citations (Scopus)

Tetrakis(dimethylamino)ethylene (TDAE)-Pd promoted reductive homo-coupling of aryl halides

Kuroboshi, M., Waki, Y. & Tanaka, H., 2002, In : Synlett. 4, p. 637-639 3 p.

Research output: Contribution to journalArticle

Nitriles
Reducing Agents
Palladium
Functional groups
Esters

繰り返し何度でも使える高性能な不斉触媒を目指して

Kuroboshi, M., 2002, In : 化学. Vol.57, No.3, p. 54-55 2 p.

Research output: Contribution to journalArticle

2001
65 Citations (Scopus)

An aqueous silica gel disperse electrolysis system. N-Oxyl-mediated electrooxidation of alcohols

Tanaka, H., Kawakami, Y., Goto, K. & Kuroboshi, M., Jan 15 2001, In : Tetrahedron Letters. 42, 3, p. 445-448 4 p.

Research output: Contribution to journalArticle

Electrolysis
Electrooxidation
Silica Gel
Alcohols
Oxidation
24 Citations (Scopus)

Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex

Tanaka, H., Kuroboshi, M., Takeda, H., Kanda, H. & Torii, S., Jul 13 2001, In : Journal of Electroanalytical Chemistry. 507, 1-2, p. 75-81 7 p.

Research output: Contribution to journalArticle

Epoxidation
Alkenes
Electrolysis
Olefins
Chlorides
68 Citations (Scopus)
Liquid Crystals
Fluorination
Desulfurization
Crystalline materials
Liquids
4 Citations (Scopus)

Substitution vs. addition. Regioselective electro-bromination of benzofuran

Tanaka, H., Kawakami, Y., Kuroboshi, M. & Torii, S., Feb 1 2001, In : Heterocycles. 54, 2, p. 825-831 7 p.

Research output: Contribution to journalArticle

Halogenation
Substitution reactions
Electrolysis
Electricity
Bromides
2000
56 Citations (Scopus)

A convenient synthesis of trifluoromethyl ethers by oxidative desulfurization-fluorination of dithiocarbonates

Kanie, K., Tanaka, Y., Suzuki, K., Kuroboshi, M. & Hiyama, T., Feb 2000, In : Bulletin of the Chemical Society of Japan. 73, 2, p. 471-484 14 p.

Research output: Contribution to journalArticle

Fluorination
Ethers
Desulfurization
Bromosuccinimide
Imides
40 Citations (Scopus)

Electro-oxidative kinetic resolution of sec-alcohols by using an optically active N-oxyl mediator

Kuroboshi, M., Yoshihisa, H., Cortona, M. N., Kawakami, Y., Gao, Z. & Tanaka, H., Oct 14 2000, In : Tetrahedron Letters. 41, 42, p. 8131-8135 5 p.

Research output: Contribution to journalArticle

Alcohols
Kinetics
Temperature
4 Citations (Scopus)
Liquid Crystals
Fluorination
Fluorine
Desulfurization
Crystalline materials
37 Citations (Scopus)

Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source: Alkenylation of aldehydes using an Ni/Cr/TDAE redox system

Kuroboshi, M., Tanaka, M., Kishimoto, S., Goto, K., Mochizuki, M. & Tanaka, H., Jan 1 2000, In : Tetrahedron Letters. 41, 1, p. 81-84 4 p.

Research output: Contribution to journalArticle

Alkenylation
Electron sources
Aldehydes
Oxidation-Reduction
Electrons
1999
30 Citations (Scopus)
Fluorination
Aromatic compounds
Desulfurization
Bromosuccinimide
N-iodosuccinimide